Scientists are closer to finding effective ways to reduce CO₂levels -- a vital part of responding to climate change and energy efficiency challenges.

一项研究由Osamu Ishitani的管理artment of Chemistry, Tokyo Tech now demonstrates the advantages of applying electrocatalysis1 to capture low-concentration CO₂.

In their study published inChemical Science, Ishitani and colleagues including Hiromu Kumagai and Tetsuya Nishikawa drew on decades of work on honing the capabilities of a rhenium-based catalyst, and demonstrated its ability to reduce low-concentration CO₂in the presence of a chemical called triethanolamine (TEOA).

Compared to many previous studies that have focused on reducing pure CO₂, few have explored how to improve direct capture of low-concentration CO₂-- a topic that warrants further investigation, considering that plants harness low concentrations of CO₂(about 400 ppm, that is 0.04% of the atmosphere) and exhaust gases from heavy industries typically contain low levels of CO₂(around 3-13%).

By avoiding the need for additional energy-consuming condensation processes, their strategy, if scaled up, could provide a more viable, environmentally friendly solution to CO₂capture in many settings.

In a series of experiments to assess electrocatalytic activity, the researchers found that at a CO₂concentration of 1%, the rhenium-based catalyst showed very high selectivity (94%) towards carbon monoxide (CO) formation.

A likely reason behind the high performance, the researchers say, is the efficient insertion of CO₂into the rhenium-oxygen bond.

The researchers aim to continue systematically investigating promising strategies to help reduce real-world CO₂levels.