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Electrode's 'hot edges' convert carbon dioxide gas into fuels and chemicals

Date:
May 14, 2019
Source:
University of Bath
Summary:
A team of scientists has created a bowl-shaped electrode with 'hot edges' which can efficiently convert carbon dioxide from gas into carbon based fuels and chemicals, helping combat the climate change threat posed by atmospheric carbon dioxide.
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A team of scientists has created a bowl-shaped electrode with 'hot edges' which can efficiently convert CO2from gas into carbon based fuels and chemicals, helping combat the climate change threat posed by atmospheric carbon dioxide.

The research team, from the University of Bath, Fudan University, Shanghai, and the Shanghai Institute of Pollution Control and Ecological Security, hopes the catalyst design will eventually allow the use of renewable electricity to convert CO2into fuels without creating additional atmospheric carbon -- essentially acting like an electrochemical 'leaf' to convert carbon dioxide into sugars.

Using this reaction, known as the reduction of carbon dioxide, has exciting potential but two major obstacles are poor conversion efficiency of the reaction and a lack of detailed knowledge about the exact reaction pathway.

This new electrode addresses these challenges with higher conversion efficiency and sensitive detection of molecules created along the reaction's progress -- thanks to its innovative shape and construction. The bowl shaped electrode works six times faster than standard planar -- or flat -- designs.

The bowl-like shape of the design, technically known as an "inverse opal structure" concentrates electric fields on its hot edges -- the rim of the bowl -- which then concentrates positively charged potassium ions on the active sites of the reaction, reducing its energy requirements.

The Copper-Indium alloy electrode can also be useful to sensitively study the reaction process via measuring the Raman signal, which is higher compared to a typical electrode.

The study is published in the材料化学杂志》上.

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Professor Ventsislav Valev, from the University of Bath's Department of Physics, said: "There is no more pressing human need than breathing. Yet for hundreds of million people this most basic activity is a source of anxiety over lowering life expectancy, rising child mortality and climate change. There is evidence that CO2increases surface ozone, carcinogens, and particulate matter, thereby increasing death, asthma, hospitalization, and cancer rates. It is therefore crucial to keep researching new ways for lowing the CO2levels in the atmosphere."

The team wants to continue research to develop the most efficient catalyst to perform carbon reduction.

Professor Liwu Zhang, from Fudan University, said: "CO2is causing climate change, making our planet warmer. By using clean electricity, we can convert CO2into chemical fuels, which can be used again. This builds a cycle of CO2, with no increment of CO2concentration and will help save our world.

"However, to improve the efficiency of transforming CO2into chemical fuels, it is extremely important to know the reaction pathway, and find the most suitable catalyst.

"Just as plants transform CO2into sugar we are finding suitable electrochemical 'leaf' for CO2conversion."

The study was funded by the Ministry of Science and Technology of the People's Republic of China, and National Natural Science Foundation of China, the Engineering and Physical Sciences Research Council(EPSRC) Centre for Doctoral Training in Condensed Matter Physics (CDT-CMP), and the Royal Society.

Story Source:

Materials provided byUniversity of Bath.Note: Content may be edited for style and length.


Journal Reference:

  1. Yang Yang, Lukas Ohnoutek, Saira Ajmal, Xiuzhen Zheng, Yiqing Feng, Kejian Li, Tao Wang, Yue Deng, Yangyang Liu, Dong Xu, Ventsislav K. Valev, Liwu Zhang.“Hot edges” in an inverse opal structure enable efficient CO2 electrochemical reduction and sensitive in situ Raman characterization.材料化学杂志》上, 2019; DOI:10.1039/C9TA02288K

Cite This Page:

University of Bath. "Electrode's 'hot edges' convert carbon dioxide gas into fuels and chemicals." ScienceDaily. ScienceDaily, 14 May 2019. .
University of Bath. (2019, May 14). Electrode's 'hot edges' convert carbon dioxide gas into fuels and chemicals.ScienceDaily. Retrieved August 2, 2023 from www.koonmotors.com/releases/2019/05/190514143246.htm
University of Bath. "Electrode's 'hot edges' convert carbon dioxide gas into fuels and chemicals." ScienceDaily. www.koonmotors.com/releases/2019/05/190514143246.htm (accessed August 2, 2023).

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