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Climate rewind: Scientists turn carbon dioxide back into coal

New technique can efficiently convert CO2from gas into solid particles of carbon

Date:
February 26, 2019
Source:
RMIT University
Summary:
Scientists have harnessed liquid metals to turn carbon dioxide back into solid coal, in research that offers an alternative pathway for safely and permanently removing the greenhouse gas from our atmosphere. The new technique can convert carbon dioxide back into carbon at room temperature, a process that's efficient and scalable. A side benefit is that the carbon can hold electrical charge, becoming a supercapacitor, so it could potentially be used as a component in future vehicles.
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FULL STORY

Researchers have used liquid metals to turn carbon dioxide back into solid coal, in a world-first breakthrough that could transform our approach to carbon capture and storage.

The research team led by RMIT University in Melbourne, Australia, have developed a new technique that can efficiently convert CO2from a gas into solid particles of carbon.

Published in the journalNature Communications, the research offers an alternative pathway for safely and permanently removing the greenhouse gas from our atmosphere.

Current technologies for carbon capture and storage focus on compressing CO2into a liquid form, transporting it to a suitable site and injecting it underground.

But implementation has been hampered by engineering challenges, issues around economic viability and environmental concerns about possible leaks from the storage sites.

RMIT researcher Dr Torben Daeneke said converting CO2into a solid could be a more sustainable approach.

"While we can't literally turn back time, turning carbon dioxide back into coal and burying it back in the ground is a bit like rewinding the emissions clock," Daeneke, an Australian Research Council DECRA Fellow, said.

“到目前为止,有限公司2has only been converted into a solid at extremely high temperatures, making it industrially unviable.

“通过使用液体etals as a catalyst, we've shown it's possible to turn the gas back into carbon at room temperature, in a process that's efficient and scalable.

"While more research needs to be done, it's a crucial first step to delivering solid storage of carbon."

How the carbon conversion works

Lead author, Dr Dorna Esrafilzadeh, a Vice-Chancellor's Research Fellow in RMIT's School of Engineering, developed the electrochemical technique to capture and convert atmospheric CO2to storable solid carbon.

To convert CO2, the researchers designed a liquid metal catalyst with specific surface properties that made it extremely efficient at conducting electricity while chemically activating the surface.

The carbon dioxide is dissolved in a beaker filled with an electrolyte liquid and a small amount of the liquid metal, which is then charged with an electrical current.

The CO2slowly converts into solid flakes of carbon, which are naturally detached from the liquid metal surface, allowing the continuous production of carbonaceous solid.

Esrafilzadeh said the carbon produced could also be used as an electrode.

"A side benefit of the process is that the carbon can hold electrical charge, becoming a supercapacitor, so it could potentially be used as a component in future vehicles."

"The process also produces synthetic fuel as a by-product, which could also have industrial applications."

The research was conducted at RMIT's MicroNano Research Facility and the RMIT Microscopy and Microanalysis Facility, with lead investigator, Honorary RMIT and ARC Laureate Fellow, Professor Kourosh Kalantar-Zadeh (now UNSW).

The research is supported by the Australian Research Council Centre for Future Low-Energy Electronics Technologies (FLEET) and the ARC Centre of Excellence for Electromaterials Science (ACES).

The collaboration involved researchers from Germany (University of Munster), China (Nanjing University of Aeronautics and Astronautics), the US (North Carolina State University) and Australia (UNSW, University of Wollongong, Monash University, QUT).

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Story Source:

Materialsprovided byRMIT University.注:内容可能edited for style and length.


Journal Reference:

  1. Dorna Esrafilzadeh, Ali Zavabeti, Rouhollah Jalili, Paul Atkin, Jaecheol Choi, Benjamin J. Carey, Robert Brkljača, Anthony P. O’Mullane, Michael D. Dickey, David L. Officer, Douglas R. MacFarlane, Torben Daeneke, Kourosh Kalantar-Zadeh.Room temperature CO2 reduction to solid carbon species on liquid metals featuring atomically thin ceria interfaces.Nature Communications, 2019; 10 (1) DOI:10.1038/s41467-019-08824-8

Cite This Page:

RMIT University. "Climate rewind: Scientists turn carbon dioxide back into coal: New technique can efficiently convert CO2from gas into solid particles of carbon." ScienceDaily. ScienceDaily, 26 February 2019. .
RMIT University. (2019, February 26). Climate rewind: Scientists turn carbon dioxide back into coal: New technique can efficiently convert CO2from gas into solid particles of carbon.ScienceDaily. Retrieved July 15, 2023 from www.koonmotors.com/releases/2019/02/190226112429.htm
RMIT University. "Climate rewind: Scientists turn carbon dioxide back into coal: New technique can efficiently convert CO2from gas into solid particles of carbon." ScienceDaily. www.koonmotors.com/releases/2019/02/190226112429.htm (accessed July 15, 2023).

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