Carbon-neutral fuels move a step closer

The researchers published their findings inScience(June 14).

Replacing gold with iron

The new process is just as efficient as previous technologies, but with one major benefit. "To date, most catalysts have used atoms of precious metals such as gold," explains Professor Hu. "But we've used iron atoms instead. At extremely low currents, our process achieves conversion rates of around 90%, meaning it performs on a par with precious-metal catalysts."

"Our catalyst converts such a high percentage of CO₂into CO because we successfully stabilized iron atoms to achieve efficient CO₂activation," adds Jun Gu, a PhD student and lead author of the paper. To help them understand why their catalyst was so highly active, the researchers called on a team led by Professor Hao Ming Chen at National Taiwan University, who conducted a key measurement of the catalyst under operating conditions using synchrotron X-rays.

Closing the carbon cycle

Although the team's work is still very much experimental, the research paves the way for new applications. At present, most of the carbon monoxide needed to make synthetic materials is obtained from petroleum. Recycling the carbon dioxide produced by burning fossil fuels would help preserve precious resources, as well as limit the amount of CO₂-- a major greenhouse gas -- released into the atmosphere.

The process could also be combined with storage batteries and hydrogen-production technologies to convert surplus renewable power into products that could fill the gap when demand outstrips supply.