结合仿真、实验和theoretical analysis, the teams of Günter Brenn at TU Graz and Dieter Bothe at TU Darmstadt have now solved the puzzle together. They've found that the interaction of the polymer molecules with the flow around the gas bubbles leads to the bubbles' strange velocity behaviour. With this knowledge, the oxygen input into these solutions can now be predicted more accurately, which means that equipment in biotechnology, process engineering and the pharmaceutical industry, for example, can be better designed. The researchers currently explain their findings in theJournal of Non-Newtonian Fluid Mechanics.

"Relaxed" state preferred

Polymers often consist of huge molecules that interact in complex ways with the liquid in which they are dissolved. This interaction makes a liquid viscoelastic. What causes the jump in velocity that gas bubbles display in these liquids from the critical diameter onwards? Günter Brenn explains the latest findings: "The flow around the bubble causes the dissolved polymer molecules to stretch. The molecules do not particularly like this state. They want to return to the relaxed, unstretched state as soon as possible." If this return to the relaxed state is faster than the transport of the molecules to the equator of the bubble, then the bubble remains slow. If, on the other hand, the return to the relaxed state takes longer than the journey to the bubbles's equator, then a tension is released in the fluid that "pushes" the bubble. This leads to a self-amplification, since subsequent polymer molecules position themselves below the equator and relax, unloading their elastic energy, releasing a "propulsive force."

In addition to the high practical relevance of this finding, especially for the above-mentioned areas of application, there are also consequences in basic research. "It turned out that another surprising property of the flow field of these solutions can be assigned to this molecular mechanism we showed: namely, the so-called 'negative wake' of the gas bubble," says Dieter Bothe from the Analysis working group of the Department of Mathematics at TU Darmstadt. This is an area in the flow field below the bubble where the fluid normally "follows" the bubble at a low velocity. With polymeric liquids, however, it is the other way round: there, the movement of the liquid is oriented in the opposite direction to the movement of the bubble. This fluid movement is caused by the same tension that "pushes" the bubble. This understanding can lead to possibilities for controlling flow processes.